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Abstract Assessing the prevalence of atmospheres on rocky planets around M-dwarf stars is a top priority of exoplanet science. High-energy activity from M dwarfs can destroy the atmospheres of these planets, which could explain the lack of atmosphere detections to date. Volcanic outgassing has been proposed as a mechanism to replenish the atmospheres of tidally heated rocky planets. L 98-59 b, a sub-Earth transiting a nearby M dwarf, was recently identified as the most promising exoplanet to detect a volcanic atmosphere. We present the transmission spectrum of L 98-59 b from four transits observed with JWST NIRSpec G395H. Although the airless model provides an adequate fit to the data based on itsχ², an SO₂atmosphere is preferred by 3.6σover a flat line in terms of the Bayesian evidence. Such an atmosphere would likely be in a steady state where volcanism balances escape. If so, L 98-59 b must experience at least eight times as much volcanism and tidal heating per unit mass as Io. If volcanism is driven by runaway melting of the mantle, we predict the existence of a subsurface magma ocean in L 98-59 b extending up toR_p ∼  60%–90%. An SO₂-rich volcanic atmosphere on L 98-59 b would be indicative of an oxidized mantle with an oxygen fugacity offO₂ > IW + 2.7, and it would imply that L 98-59 b must have retained some of its volatile endowment despite its proximity to its star. Our findings suggest that volcanism may revive secondary atmospheres on tidally heated rocky planets around M dwarfs. 

Abstract High-resolution spectroscopy of exoplanet atmospheres provides insights into their composition and dynamics from the resolved line shape and depth of thousands of spectral lines. WASP-127 b is an extremely inflated sub-Saturn (R_p= 1.311R_Jup,M_p= 0.16M_Jup) with previously reported detections of H₂O and CO₂. However, the seeming absence of the primary carbon reservoir expected at WASP-127 b temperatures (T_eq∼1400 K) from chemical equilibrium, CO, posed a mystery. In this manuscript, we present the analysis of high-resolution observations of WASP-127 b with the Immersion Grating Infrared Spectrometer on Gemini South. We confirm the presence of H₂O (8.67σ) and report the detection of CO (4.34σ). Additionally, we conduct a suite of Bayesian retrieval analyses covering a hierarchy of model complexity and self-consistency. When freely fitting for the molecular gas volume mixing ratios, we obtain super-solar metal enrichment for H₂O abundance of log₁₀X ${}_{{\mathrm{H}}_2\mathrm{O}}$= −1.23 ${}_{-0.49}^{+0.29}$and a lower limit on the CO abundance of log₁₀X_CO≥–2.20 at 2σconfidence. We also report tentative evidence of photochemistry in WASP-127 b based upon the indicative depletion of H₂S. This is also supported by the data preferring models with photochemistry over free-chemistry and thermochemistry. The overall analysis implies a super-solar (∼39× Solar; [M/H] = ${1.59}_{-0.30}^{+0.30}$) metallicity for the atmosphere of WASP-127 b and an upper limit on its atmospheric C/O ratio as < 0.68. 

Abstract A primary goal of exoplanet science is to measure the atmospheric composition of gas giants in order to infer their formation and migration histories. Common diagnostics for planet formation are the atmospheric metallicity ([M/H]) and the carbon-to-oxygen (C/O) ratio as measured through transit or emission spectroscopy. The C/O ratio in particular can be used to approximately place a planet’s initial formation radius from the stellar host, but a given C/O ratio may not be unique to formation location. This degeneracy can be broken by combining measurements of both the C/O ratio and the atmospheric refractory-to-volatile ratio. We report the measurement of both quantities for the atmosphere of the canonical ultrahot Jupiter WASP-121 b using the high-resolution (R= 45,000) IGRINS instrument on Gemini South. Probing the planet’s direct thermal emission in both pre- and post-secondary eclipse orbital phases, we infer that WASP-121 b has a significantly superstellar C/O ratio of ${0.70}_{-0.10}^{+0.07}$and a moderately superstellar refractory-to-volatile ratio at ${3.83}_{-1.67}^{+3.62}\times$stellar. This combination is most consistent with formation between the soot line and H₂O snow line, but we cannot rule out formation between the H₂O and CO snow lines or beyond the CO snow line. We also measure velocity offsets between H₂O, CO, and OH, potentially an effect of chemical inhomogeneity on the planet dayside. This study highlights the ability to measure both C/O and refractory-to-volatile ratios via high-resolution spectroscopy in the near-IRHandKbands. 

Abstract Ground-based high-resolution and space-based low-resolution spectroscopy are the two main avenues through which transiting exoplanet atmospheres are studied. Both methods provide unique strengths and shortcomings, and combining the two can be a powerful probe into an exoplanet’s atmosphere. Within a joint atmospheric retrieval framework, we combined JWST NIRSpec/G395H secondary eclipse spectra and Gemini South/IGRINS pre- and post-eclipse thermal emission observations of the hot Jupiter WASP-77A b. Our inferences from the IGRINS and NIRSpec data sets are consistent with each other, and combining the two allows us to measure the gas abundances of H₂O and CO, as well as the vertical thermal structure, with higher precision than either data set provided individually. We confirm WASP-77A b’s subsolar metallicity ([(C+O)/H] = −0.61 ${}_{-0.09}^{+0.10})$and solar C/O ratio (C/O = 0.57 ${}_{-0.06}^{+0.06})$. The two types of data are complementary, and our abundance inferences are mostly driven by the IGRINS data, while inference of the thermal structure is driven by the NIRSpec data. Our ability to draw inferences from the post-eclipse IGRINS data is highly sensitive to the number of singular values removed in the detrending process, potentially due to high and variable humidity. We also search for signatures for atmospheric dynamics in the IGRINS data and find that propagated ephemeris error can manifest as either an orbital eccentricity or a strong equatorial jet. Neither are detected when using more up-to-date ephemerides. However, we find moderate evidence of thermal inhomogeneity and measure a cooler nightside that presents itself in the later phases after secondary eclipse. 

Abstract The characterization of young planets (<300 Myr) is pivotal for understanding planet formation and evolution. We present the 3–5μm transmission spectrum of the 17 Myr, Jupiter-size (R∼10R_⊕) planet, HIP 67522b, observed with JWST NIRSpec/G395H. To check for spot contamination, we obtain a simultaneousg-band transit with the Southern Astrophysical Research Telescope. The spectrum exhibits absorption features 30%–50% deeper than the overall depth, far larger than expected from an equivalent mature planet, and suggests that HIP 67522b’s mass is <20M_⊕irrespective of cloud cover and stellar contamination. A Bayesian retrieval analysis returns a mass constraint of 13.8 ± 1.0M_⊕. This challenges the previous classification of HIP 67522b as a hot Jupiter and instead, positions it as a precursor to the more common sub-Neptunes. With a density of <0.10 g cm⁻³, HIP 67522 b is one of the lowest-density planets known. We find strong absorption from H₂O and CO₂(≥7σ), a modest detection of CO (3.5σ), and weak detections of H₂S and SO₂(≃2σ). Comparisons with radiative-convective equilibrium models suggest supersolar atmospheric metallicities and solar-to-subsolar C/O ratios, with photochemistry further constraining the inferred atmospheric metallicity to 3 × 10 solar due to the amplitude of the SO₂feature. These results point to the formation of HIP 67522b beyond the water snowline, where its envelope was polluted by icy pebbles and planetesimals. The planet is likely experiencing substantial mass loss (0.01–0.03M_⊕Myr⁻¹), sufficient for envelope destruction within a gigayear. This highlights the dramatic evolution occurring within the first 100 Myr of its existence. 

Abstract Tidal heating on Io due to its finite eccentricity was predicted to drive surface volcanic activity, which was subsequently confirmed by the Voyager spacecraft. Although the volcanic activity in Io is more complex, in theory volcanism can be driven by runaway melting in which the tidal heating increases as the mantle thickness decreases. We show that this runaway melting mechanism is generic for a composite planetary body with liquid core and solid mantle, provided that (i) the mantle rigidity,μ, is comparable to the central pressure, i.e.,μ/(ρgR_P) ≳ 0.1 for a body with densityρ, surface gravitational accelerationg, and radiusR_P; (ii) the surface is not molten; (iii) tides deposit sufficient energy; and (iv) the planet has nonzero eccentricity. We calculate the approximate liquid core radius as a function ofμ/(ρgR_P), and find that more than 90% of the core will melt due to this runaway forμ/(ρgR_P) ≳ 1. From all currently confirmed exoplanets, we find that the terrestrial planets in the L 98-59 system are the most promising candidates for sustaining active volcanism. However, uncertainties regarding the quality factors and the details of tidal heating and cooling mechanisms prohibit definitive claims of volcanism on any of these planets. We generate synthetic transmission spectra of these planets assuming Venus-like atmospheric compositions with an additional 5%, 50%, and 98% SO₂component, which is a tracer of volcanic activity. We find a ≳3σpreference for a model with SO₂with 5–10 transits with JWST for L 98-59bcd. 

Abstract Kepler-51 is a ≲1 Gyr old Sun-like star hosting three transiting planets with radii ≈6–9R_⊕and orbital periods ≈45–130 days. Transit timing variations (TTVs) measured with past Kepler and Hubble Space Telescope (HST) observations have been successfully modeled by considering gravitational interactions between the three transiting planets, yielding low masses and low mean densities (≲0.1 g cm⁻³) for all three planets. However, the transit time of the outermost transiting planet Kepler-51d recently measured by the James Webb Space Telescope 10 yr after the Kepler observations is significantly discrepant from the prediction made by the three-planet TTV model, which we confirmed with ground-based and follow-up HST observations. We show that the departure from the three-planet model is explained by including a fourth outer planet, Kepler-51e, in the TTV model. A wide range of masses (≲M_Jup) and orbital periods (≲10 yr) are possible for Kepler-51e. Nevertheless, all the coplanar solutions found from our brute-force search imply masses ≲10M_⊕for the inner transiting planets. Thus, their densities remain low, though with larger uncertainties than previously estimated. Unlike other possible solutions, the one in which Kepler-51e is around the 2:1 mean motion resonance with Kepler-51d implies low orbital eccentricities (≲0.05) and comparable masses (∼5M_⊕) for all four planets, as is seen in other compact multiplanet systems. This work demonstrates the importance of long-term follow-up of TTV systems for probing longer-period planets in a system. 

Abstract The recent inference of sulfur dioxide (SO₂) in the atmosphere of the hot (approximately 1,100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations^1–3suggests that photochemistry is a key process in high-temperature exoplanet atmospheres⁴. This is because of the low (<1 ppb) abundance of SO₂under thermochemical equilibrium compared with that produced from the photochemistry of H₂O and H₂S (1–10 ppm)^4–9. However, the SO₂inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 μm and, therefore, the detection of other SO₂absorption bands at different wavelengths is needed to better constrain the SO₂abundance. Here we report the detection of SO₂spectral features at 7.7 and 8.5 μm in the 5–12-μm transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS)¹⁰. Our observations suggest an abundance of SO₂of 0.5–25 ppm (1σrange), consistent with previous findings⁴. As well as SO₂, we find broad water-vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 μm. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy-element content (metallicity) for WASP-39b of approximately 7.1–8.0 times solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range. 

Abstract Close-in giant exoplanets with temperatures greater than 2,000 K (‘ultra-hot Jupiters’) have been the subject of extensive efforts to determine their atmospheric properties using thermal emission measurements from the Hubble Space Telescope (HST) and Spitzer Space Telescope^1–3. However, previous studies have yielded inconsistent results because the small sizes of the spectral features and the limited information content of the data resulted in high sensitivity to the varying assumptions made in the treatment of instrument systematics and the atmospheric retrieval analysis^3–12. Here we present a dayside thermal emission spectrum of the ultra-hot Jupiter WASP-18b obtained with the NIRISS¹³instrument on the JWST. The data span 0.85 to 2.85 μm in wavelength at an average resolving power of 400 and exhibit minimal systematics. The spectrum shows three water emission features (at >6σconfidence) and evidence for optical opacity, possibly attributable to H⁻, TiO and VO (combined significance of 3.8σ). Models that fit the data require a thermal inversion, molecular dissociation as predicted by chemical equilibrium, a solar heavy-element abundance (‘metallicity’,$${\rm{M/H}}=1.0{3}_{-0.51}^{+1.11}$$ $\mathrm{M/H}=1.03_{-0.51}^{+1.11}$times solar) and a carbon-to-oxygen (C/O) ratio less than unity. The data also yield a dayside brightness temperature map, which shows a peak in temperature near the substellar point that decreases steeply and symmetrically with longitude towards the terminators.